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| CD 1: Original album (released as Mercury MERH58, 1985) and B-sides: | |
| 1. Shout | |
| 2. The Working Hour | |
| 3. Everybody Wants to Rule the World | |
| 4. Mothers Talk | |
| 5. I Believe | |
| 6. Broken | |
| 7. Head Over Heels | |
| 8. Listen | |
| 9. The Big Chair (B-side to "Shout" - Mercury IDEA 8, 1984) | |
| 10. Empire Building (B-side to "Mothers Talk" - Mercury IDEA 7, 1984) | |
| 11. The Marauders (B-side to "The Way You Are" - Mercury IDEA 6, 1983) | |
| 12. Broken Revisited (from limited edition cassette album - Mercury MERHC58, 1985) | |
| 13. The Conflict (B-side to "Change" - Mercury IDEA 4, 1983) | |
| 14. The Working Hour (Piano Version) (from limited edition cassette album - Mercury MERHC58, 1985) | |
| 15. Pharoahs (B-side to "Everybody Wants to Rule the World" - Mercury IDEA 9, 1985) | |
| 16. When in Love with a Blind Man (B-side to "Head Over Heels" - Mercury IDEA 10, 1985) | |
| 17. Sea Song (B-side to "I Believe" - Mercury IDEA 11, 1985) | |
| . | |
| CD 2 - Edited Songs from the Big Chair: | |
| 1. The Way You Are (Mercury IDEA 6, 1983) | |
| 2. Mothers Talk (7" Version) (Mercury IDEA 7, 1984) | |
| 3. Shout (7" Version) (Mercury IDEA 8, 1984) | |
| 4. Everybody Wants to Rule the World (7" Version) (Mercury IDEA 9, 1985) | |
| 5. Head Over Heels (David Bascombe 7" Mix) (Mercury IDEA 10, 1985) | |
| 6. I Believe (A Soulful Re-Recording) (Mercury IDEA 11, 1984) | |
| 7. Everybody Wants to Run the World (Mercury RACE 1, 1986) | |
| 8. The Way You Are (Short Version) (promo A-side - Mercury IDADJ 6, 1983) | |
| 9. Mothers Talk (U.S. Remix) (Mercury 884 638-7 (U.S.), 1986) | |
| 10. Shout (U.S. Single Version) (Mercury 880 294-7 (U.S.), 1985) | |
| 11. Everybody Wants to Run the World (Running Version) (B-side to Mercury RACE 1, 1986) | |
| 12. Head Over Heels (Chris Hughes 7" Edit) (Philips S/N 577 (MX), 1986) | |
| 13. Mothers Talk (Video Version) (released on Songs from the Big Chair (Deluxe Edition) - Mercury/UMC 3794991 (U.K.), 2014) | |
| 14. Shout (Short Version) (Mercury 880 441-7 (DE), 1984) | |
| 15. Listen (Clean Intro) (released on Songs from the Big Chair (Deluxe Edition) - Mercury/UMC 3794991 (U.K.), 2014) | |
| 16. Interview with Curt and Roland (B-side to "Everybody Wants to Rule the World" double 7" - Mercury IDEA 99, 1985) | |
| . | |
| CD 3: Remixed Songs from the Big Chair | |
| 1. The Way You Are (Extended Version) (Mercury IDEA 612, 1983) | |
| 2. Mothers Talk (Extended Mix) (Mercury IDEA 712, 1984) | |
| 3. Shout (Extended Version) (Mercury IDEA 812, 1984) | |
| 4. Everybody Wants to Rule the World (Extended Mix) (Mercury IDEA 912, 1985) | |
| 5. Broken/Head Over Heels (Preacher Mix) (Mercury IDEA 1012, 1985) | |
| 6. Mothers Talk (Beat of the Drum Mix) (Mercury IDEA R712, 1984) | |
| 7. Shout (U.S. Remix) (Mercury 880 929-1 (U.S.), 1985) | |
| 8. Everybody Wants to Rule the World (Urban Mix) (Mercury IDER 912, 1985) | |
| 9. Mothers Talk (Alternate U.S. Remix) (from Songs from the Big Chair (Deluxe Edition) - Mercury/Chronicles B0006691-02 (U.S.), 2006) | |
| 10. Shout (Dub) (Mercury promo PRO 366-1 (U.S.), 1985) | |
| 11. Everybody Wants to Rule the World (Instrumental) (B-side to Mercury IDER 912, 1985) | |
| 12. Shout (A Capella) (Mercury promo PRO 366-1 (U.S.), 1985) | |
